Silica sol doped with organic pigment was prepared by hydrolyzing tetraethoxysilane with a basic catalyst via dispersing pigment in silica sol. The colloidal properties of SiO2/pigment hybrid sol and its deposited film were investigated. The presence of pigment in SiO2/pigment hybrid sol affects the Zeta potential, particle size and surface tension compared to the silica sol without pigment. The SiO2/pigment hybrid sol exhibited good dispersion stability in the centrifuge process. The maximum absorption wavelength was consistent with that of the pigment disperse solution, indicating that the pigment in SiO2/pigment hybrid sol remained unchanged. Thermogravimetric analysis of the contents of organic component in silica sol and SiO2/pigment hybrid sol were conducted, and the differential value was ascribed to the weight of the pigment
and the condensate of polyoxyethylene octylphenol ether (OP-10) and c-Glycidoxypropyltrimethoxysilane (KH-560). The surface topography of SiO2/pigment hybrid silica film was characterized by AFM. The analysis of silica sol doped with organic pigment provides useful information for an effective pathway to disperse pigment on fiber and other substrates.