The electron paramagnetic resonance (EPR) technique was employed to investigate the point defects in barium strontium titanate ceramics. All samples showed a strong EPR signal with g =2.000, which was indexed as intrinsic Ti-vacancy defects. In (Ba0.85Sr0.15)TiO3 ceramic, which showed a tetragonal symmetry and consisted of the crystallites with average size of ~ 220 nm, a novel EPR powder spectrum was observed - the g-factor of the g = 2.000 signal evolved into a g-tensor, and the two weak signals with g3 = ~ 2.6 and g1 = ~ 1.6 gradually shifted toward the g2 = 2.000 signal and
approached to each other with increasing temperature

论文下载
作者

Da-Yong Lu,and Xiu-Yun Sun

期刊

Advanced Materials Research

年份